No. If you'd like to give yourself extra address (also called an alias), you'll need to visit your Email Control Panel. Here's how:
On our Getting Started page, click the "Web Hosting Control Panel" link at the top of the page.

Now click the Email tab.

Click "Add Aliases."

Follow the directions to create the alias.
Messages sent to this alias will go straight to your inbox, so you can send and receive email from several different email addresses. Learn more about aliases.