To send an IM to someone that you have not added to your Messenger List:
Note: If you enter an ID that does not exist, you will receive the following error message: "The message for user 'username' was not saved. Please verify the recipient's name and try again. Thank you."
To send an IM to a contact that you have added to your Messenger List:
Note: You can send an IM to a person who is offline. The next time the person comes online, your message will pop up automatically.